By 鈴木, 基之, 1941- 鈴木, 基之, ; Motoyuki Suzuki
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Additional resources for Adsorption engineering
Molecular probe method. A. mercury penetration method By applying pressure, P, to mercury surrounding a porous body, mercury penetrates into the pores whose radii are larger than r given by the following equation r=- 20 cos e P where a represents the surface tension of mercury, 470dynelcrn (298 K), 8 is the contact angle between mercury and the sample Electr~c br~dge Pressure Constant temperature bath Flg 2 1 1 Mercury penetration apparatus. Measurement of Pore-related Properties 25 surface, which is usually taken as 140°C.
In the case of two components, the extended Langmurr isotherm (Markham and Benton, 1931) is given as Thls equatron enables qurck est~matron of equilibrium relatrons of Adsorprron Isotherms for Multtcomponent Systems 57 multicomponent adsorption from Langmuir parameters determined from the single component isotherm of each component. Eq. ( 3 4 2 ) is thermodynamically consistent when 901= 902 holds. Furthermore, the equation can be applied without significant error to a combination of different values of qo if the components are similar in natureand follow the Langmuir isotherm relation.
W(A) is the adsorption characteristic curve originally introduced by Polanyi (1914) and Berenyi (1920). Adsorption of benzene on activated carbon is plotted in Fig. 8 in the form of the characteristic curve. Dubinin (1960) assumed a distribution of the Gaussian type for the characteristic curve and derived the following, which is called DubininRadushkevich equation. Adsorption equilibrium relation of benzene on two types of activated carbon are plotted by the Langmuir plot and the Dubinin plot in Fig.